I don't think it's a condensing boiler....
http://www.ferroli.co.uk/product_documentation/DOMESTIC_ARCHIVE/Optima_1001_Manu...Looks like the Pressure Relief Valve and/or the expansion vessel should be checked.
The expansion vessel is basically an air filled chamber designed to accomodate the expansion of the water when the systems heats up. If it's lost it's charge or become faulty the water has nowhere to go and the pressure rises too much. If the pressure goes high enough the PRV open and you get water out the pipe. When system cools down again the pressure then falls below normal.
It's possible the expansion vessel just needs recharging (with a car tyre foot pump). The proceedure for checking this and recharging hss been posted on previous threads.