Hello Veeves
You're problem sounds strange to me, pressing the 'T' or 'Test' button on the RCD, should not trip you're MCB..
Not sure what else to add, could be that it just happened the same time as another fault on the ring, or that the SRCD (Socket Outlet Incorporating Residual Current Device) is fault...
May I ask why if it work's first time, do you proceed to test again?, nothing wrong with testing, but trying to build up a picture of what's happening