corablimey
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I have never painted pipes or radiators with radiator paint, I have always used oil-based paint, and they have looked really nice, and they have lasted. To keep your rad staying white much longer if you have a quick hand, and a big brush lol, try and do the top coat, eg gloss, with the rad on, this will stop the paint from yellowing.
For your pipes, I would undercoat with oilbase U/C that stops them turning green, any oilbase stops them turning green, if you want them white, then you would U/C a couple of times, then either satinwood or gloss as atop coat, again in Oilbase.
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